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Jubrail
(Hive Bee) 07-05-03 05:59 No 444680 |
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Simple question (curiosity) | Bookmark | |||||
This is an orgo. theory question: If I have a benzene ring with NH2 attached and want to replace this with COOH: _ _ / \_NH2 --> / \_COOH \_/ \_/ I believe that the text book way to do this is to convert the molecule to a disulfide salt with NaNO2 and HCl, then use Cupric Cyanide / Potassium CN to change it into a benzen ring with a CN on it. Then it can be reacted in an acidic aqueous solution to get the desired molecule. First off, is this correct? Secondly, is there another route that can be used? No, I am not a college orgo student, that needs help on his homework. I am an ignorant man trying to teach myself some chemistry. Rainbows & Butterflies Forever :) |
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Osmium (Stoni's sexual toy) 07-05-03 06:42 No 444685 |
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1. NaNO2/H(+) ----> diazonium compound 2. | Bookmark | |||||
1. NaNO2/H(+) ----> diazonium compound 2. React with CuCN ----> benzonitrile 3. hydrolyse to produce the acid I'm not fat just horizontally disproportionate. http://www.whatreallyhappened.com |
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Jubrail (Hive Bee) 07-05-03 07:35 No 444690 |
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Thanks, Os | Bookmark | |||||
But my question was if that was the only path to the final compound? Rainbows & Butterflies Forever :) |
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acid_egg (Hive Addict) 07-05-03 07:45 No 444693 |
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the one pot low yield method | Bookmark | |||||
http://www.chem.leeds.ac.uk/delights/tex ...and you may have some problems retrieving the product. ![]() |
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Jubrail (Hive Bee) 07-05-03 08:13 No 444697 |
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Thanks | Bookmark | |||||
Definitely appreciated. I can now sleep at night. Rainbows & Butterflies Forever :) |
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