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Aurelius
(Active Asperger Archivist) 07-14-03 11:18 No 447146 |
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Guiafenesin | Bookmark | |||||
What would happen to this compound upon Claissen Rearrangment? the possibility of a usable compound from gakk sparked my interest. Post 414593 (badbody: "Guaifenesin", Stimulants) Act quickly or not at all. |
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Rhodium (Chief Bee) 07-14-03 16:59 No 447264 |
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Guaifenesin doesn't do Claisen Rearrangements | Bookmark | |||||
You can only perform Claisen Rearrangements on allylic ethers. Guaifenesin has no aliphatic double bond anywhere, so it won't react that way. |
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Aurelius (Active Asperger Archivist) 07-14-03 19:04 No 447298 |
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Rhodium | Bookmark | |||||
Dehydration. Act quickly or not at all. |
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Rhodium (Chief Bee) 07-15-03 07:13 No 447463 |
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Dehydration followed by Claisen | Bookmark | |||||
Well, in the case it was first dehydrated to the allyl ether, the major product would be 2-hydroxy-3-methoxy-allylbenzene (I doubt that would be usable) and the minor product would be eugenol... |
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Aurelius (Active Asperger Archivist) 07-15-03 07:18 No 447466 |
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Thanks | Bookmark | |||||
It was worth a shot. I just looked at that molecule and said " hey, it'd be great if they handed us precursors." But alas, it was not to be. oh well. Act quickly or not at all. |
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