07-29-04 06:48
No 522396
Is there any organic oxidation reaction in which chlorate and/or perchlorate ion could be used in place of permanganate ion, dichromate ion, H2O2, etc.? I know that chlorates and perchlorates are strong oxidizing agents, but I have searched at length on the web and found no organic reactions that utilize them.
(Hive Bee)
07-31-04 01:33
No 522794
First a bit about ......
Oxides and Oxoacids
There are no fluorine oxides as F is more electronegative than O. Chlorine, bromine and iodine each form several oxides which are thermally unstable, such as chlorine dioxide ClO2. The only fluorine oxoacid, HOF, is unstable at room temperature, but there are many oxoacids of the other halogens. The best known salts of these are; hypochlorite, chlorate(I) CIO-, chlorite, chlorate(III) ClO2-, hypochlorate, chlorate(V) CIO3-, perchlorate, chlorate(VII) ClO4- . These are all powerful oxidising agents.
Your basic search found this,
../rhodium /ptc.nao
this example found using goggle,
Example of Oxidation of Alcohols: Preparation of Cyclohexanone using hypochlorate...
I hope this helps you on your search........java
Just hold on to the thread...that keeps us going
http://www.chiapaslink.ukgateway.net/
(Newbee)
07-31-04 04:12
No 522826
I know that there are many applications for hypochlorite, but I was asking specifically about chlorates and perchlorates. I find it strange that there are no applications for them, even though there are strong oxidizers.
(Hive Bee)
07-31-04 08:33
No 522885
Post 363228 (Rhodium: "Free Online Chemistry & Medicinal Journals", Novel Discourse)
orgsyn and thieme are in my bookmarks, so i took a peek to see what was there. there are applications, you just haven't utilized what is available.
just for fun, i searched the organic database of ChemWeb (http://www.chemweb.com)
642 hits for chlorate and perchlorate.
http://www.mindstates.org