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Aurelius
(Hive Bee) 11-21-02 15:37 No 381970 |
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Decarboxylation | ||||||
What factors contribute to the ease of a decarboxylation by heat? (as in Ritter's decarboxylation in high bp ketones) how easy would it be to decarboxylate the product in the first step of ../rhodium /alpha-m |
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Rhodium (Chief Bee) 11-21-02 19:42 No 382089 |
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Decarboxylation of alpha-methyl-cinnamic acid (Rated as: good read) |
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alpha-methyl-cinnamic acid -> cis-propenylbenzene (Reflux, Quinoline, Copper powder) J. Chem. Soc. Perkin Trans. 1, 10, 2491-2498 (1982) alpha-methyl-cinnamic acid -> 2-bromo-propenylbenzene (NaBr, Oxone, Na2CO3(aq), 20°C) ../rhodium/pdf /cinnamic.halo |
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Aurelius (Hive Bee) 11-21-02 21:14 No 382133 |
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wow | ||||||
Hey Rhodium, it's horrible that you will never fully understand the gratitude aurelius has for you. thanks again!!! ![]() |
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Rhodium (Chief Bee) 11-21-02 21:33 No 382144 |
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I'd be very glad if you could send your results ... | ||||||
I'd be very glad if you could send your results back to me with a full writeup. ![]() |
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Rhodium (Chief Bee) 12-02-02 23:58 No 385769 |
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Aurelius: Here you go with another article - ... (Rated as: good read) |
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Aurelius: Here you go with another article - ../rhodium/pdf /cinnamic.oxid |
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pHarmacist (pHantasticant) 11-17-03 02:49 No 471347 |
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cinnamic acid | ||||||
Speaking about cinnamic acid derivatives, I've seen in Synthesis or Syntlett, route to nitrostyrenes from cinnamic acids + 15% HNO3 and T of -30 - 0 Celsius + MW from domestic owen, reaction gave excellent yields of nitrostyrenes. http://www.bassdrive.com/BassDrive.m3u |
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Rhodium (Chief Bee) 11-17-03 04:57 No 471359 |
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more details? | ||||||
Nice, but could you post the actual citation for that article? (Thieme's site includes a search engine if you lack any notes) |
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pHarmacist (pHantasticant) 11-17-03 07:50 No 471382 |
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Hmm.. | ||||||
I'll get it, I have the off-line copy at my mums place and I don't know more that that. However, at a bit higher temperatures 0 < T, the nitration takes place also on the ring, but at -30 it dosen't, at even higher temperatures the explosive picric acid (spellcheck) is a byproduct. http://www.bassdrive.com/BassDrive.m3u |
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Chromic (Synaptic Self-Mutilator) 11-18-03 09:41 No 471598 |
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Couldn't find it | ||||||
I did a quick search on thieme, but couldn't find it... looking for the keywords, nitrostyrene, nitric or microwave or combinations thereof. |
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