metanoid
(Stranger)
07-20-04 00:39
No 520388
       IBX Esters with Bleach!
(Rated as: excellent) 		    

this is fantastic!

step 1. turn a 2-iodobenzoic acid ester into the corresponding  ibx ester with bleach

step 2. benzyl alcohol -> benzaldehyde 100%

step 3. lots and lots of other oxidations.

here are the gooodies.

  
 
 
 
    Rhodium
(Chief Bee)
08-12-04 19:57
No 525173
       Preparation of 2-iodoxybenzoate (IBX) esters
(Rated as: excellent) 		    

Preparation and structure of 2-iodoxybenzoate esters: soluble and stable periodinane oxidizing reagents
V.V. Zhdankin, D.N. Litvinov, A.Y. Koposov, T. Luu, M.J. Ferguson, R. McDonald, R.R. Tykwinski
Chem. Commun.,(1), 106-107 (2004), DOI:10.1039/b312961f



Abstract
Esters of 2-iodoxybenzoic acid (IBX-esters) are potentially valuable oxidizing reagents belonging to a new class of pentavalent iodine compounds with a pseudo benziodoxole structure.


Full Text:

Supplementary Data (Microsoft Word format, 117 KB): Synthetic and characterization data for all new compounds (http://www.rsc.org/suppdata/cc/b3/b312961f/b312961f.doc)
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