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L42L
(Newbee) 06-23-04 00:57 No 514846 |
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Nitro alkEne direct to amine !?!?! | ||||||
Nitro alkEne direct to amine !?!?! Have been gone awhile and what do I find at Rhodium, nitro-alkene direct to amine! See “Reduction of Nitroalkenes and Nitroalkanes to Amines Using NaBH4/NiCl2 and Ultrasound” at Rhodium The only time I have heard of such an OTCish method it was some low yielding electro chem divided cell head-ache. I tried a few key words in the search engine but failed to see any discussion on this method. So I have some questions (three really), maybee some bee may have some thoughts. OK so think TMA-2, 1. In the article they use 1-nitro-cyclohexene (BTW, WTF is the diff between that and 1-nitro-cyclohex-1-ene (see article reactant table)) not exactly TM-nitropropenes twin. Any bee care to speculate how the nitrosytrene of asarone would act in this situation? 2. The article lacks any detail concerning the sonication, I wonder if an ultrasonic jewelry cleaner would do the trick? Any thoughts? 3. So from vac distilled Indian calamus oil, Nitroalkenes from Alkenes using NaNO2/I2/Ethylene Glycol (see Rhodium) and then, Reduction of Nitroalkenes and Nitroalkanes to Amines Using NaBH4/NiCl2 and Ultrasound (see Rhodium) catch my drift? Any thoughts are greatly appreciated! |
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Antibody2 (LinguisticBee) 06-26-04 21:19 No 515579 |
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this one doesn't require sonification | ||||||
../rhodium /nitrost ![]() We are all just witnesses. |
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