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Rhodium
(Chief Bee) 10-08-02 06:16 No 365809 |
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1 atm Catalytic Hydrogenation NaBH4-Ni Acetate | Bookmark | |||||
../rhodium/pdf /borohydride.p Nickel(II)Acetate tetrahydrate and sodium borohydride easily reduces a variety of alkenes alkynes and dienes selectively. Perhaps it can reduce nitroalkenes too? |
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Osmium (Stoni's sexual toy) 10-08-02 15:35 No 366021 |
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Haven't looked at it (too tired, lazy and ... | Bookmark | |||||
Haven't looked at it (too tired, lazy and confused right now) but me thinks to reduce nitroalkenes you generally need a strong, fast and nonselective catalyst+reducing agent system under more drastic condidions, not a selective one. I'm not fat just horizontally disproportionate. |
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Barium (Hive Bee) 10-08-02 15:54 No 366028 |
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I´ve made and tried both P1- and P2-NiB/NaBH4 and ... | Bookmark | |||||
I´ve made and tried both P1- and P2-NiB/NaBH4 and got quite good results from reducing both ketoximes and nitroalkanes, but crap when tried with nitroalkenes. Catalytic hydrogenation freak |
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Rhodium (Chief Bee) 10-08-02 17:38 No 366059 |
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Can you fuel the above hydrogenation by in situ ... | Bookmark | |||||
Can you fuel the above hydrogenation by in situ generation of hydrogen from NaBH4, or do you have to generate it externally? |
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Barium (Hive Bee) 10-08-02 18:43 No 366081 |
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Both the P1- and P2-NiB was generated externally ... | Bookmark | |||||
Both the P1- and P2-NiB were generated externally and the H2(g) internally. Catalytic hydrogenation freak |
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