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pHarmacist
(Hive Addict) 01-31-03 05:49 No 402934 |
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High yield PSDIB Oxidation of Alcohols (1°/2°) | Bookmark | |||||
Abstract: Primary and secondary alcohols were successfully oxidized to the corresponding aldehydes and ketones in good yields, respectively, with poly[4-(diacetoxyiodo)styrene] (PSDIB) in the presence of TEMPO (cat.) in acetone, as an environment-friendly method. This is an example of selective, less toxic (especially, non-metallic), and secure oxidation of primary and secondary alcohols to the corresponding aldehydes and ketones, respectively, under mild conditions. Synthesis 2003, No. 1, 21–23 http://pharmacist8.tripod.com/PSDIB.pdf Accept No Imitations, There Can Only Bee One; www.the-hive.ws |
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