Imines from alcohols in one pot. , Hive Novel Discourse


		Rhodium (Chief Bee) 01-26-04 07:46 No 484617				Imines from alcohols in one pot. (Rated as: good read)
						In Situ Oxidation-Imine Formation-Reduction Routes from Alcohols to Amines Leonie Blackburn and Richard J. K. Taylor Org. Lett. 3(11) 1637-1639 (2001) (../rhodium/pdf /alcohol2amine.pscbh.pdf) DOI:10.1021/ol015819b Abstract Manganese dioxide is employed as an in situ oxidant for the one-pot conversion of alcohols into imines. In combination with polymersupported cyanoborohydride (PSCBH), a one-pot oxidation-imine formation-reduction sequence is reported. This procedure enables alcohols to be converted directly into both secondary and tertiary amines. ^{The Hive - Clandestine Chemists Without Borders}