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Vibrating_Lights
(Hive Addict) 02-06-03 05:52 No 404947 |
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Reduction of amides | Bookmark | |||||
If one was to have some 4-acetoxyindol-3-yl-N,N-diethylglyoxylam VL_ He who holds the LSD holds the keys. |
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Rhodium (Chief Bee) 02-06-03 09:19 No 405002 |
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Ac2O is needed | Bookmark | |||||
Please do not open two threads about the synthesis of the same compound. But anyway, acetic acid is definitely not of any use to make the psilocin O-Acetyl ester. |
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Barium (Hive Addict) 02-06-03 10:24 No 405020 |
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Red-Al or, possibly, sodium ... | Bookmark | |||||
Red-Al or, possibly, sodium triacetoxyborohydride formed in situ from sodium borohydride and GAA. Freaky |
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Lilienthal (Moderator) 02-06-03 10:56 No 405034 |
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Sodium borohydride / acetic acid bears the... | Bookmark | |||||
Sodium borohydride / acetic acid bears the risk of reducing the indolic system to an indoline (2,3-doublebond hydrogenation). As far as I know a Clemmenson reduction only reduces keto groups adjacent to aromatic rings, so if it works, you would end up with the amide. |
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