02-27-02 00:34
No 274147
How does one work out what isomer will be form (d or l or both) from a given reaction?? MOP knows that l-pseudo goes to d-meth via the RPIE reaction - is the naming of the l and d arbitary or do things change around during the reaction?
I wouldn't do that if I were you.....
(Distinctive Doe)
02-27-02 01:06
No 274157
MOP knows that l-pseudo goes to d-meth via the RPIE reaction - is the naming of the l and d arbitary or do things change around during the reaction?
Its not arbitrary, the chrial carbon which the "l-" in l-pseudo refers to is the one that has the -OH group, remove the -OH group and this carbon is no longer chrial. The "d-" in d-meth refers to the carbon that has the nitrogen attached, this carbon is unaffected in the reaction and its orientation is "d-" in pseudoephedrine, ephedrine and d-methamphetamine.
I am unsure if my nomenclature is correct but thats why
Learn more at these sites
http://ep.llnl.gov/msds/orgchem/stereoch
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(Newbee)
02-27-02 04:19
No 274246
To put it simply:
For whatever reason, pseudo doesn't switch. d-pseudo produces d-meth. l-pseudo is very uncommon. Also, it is more expenisive than d-pseudo. Ephedrine switches though; l-eph makes d-meth and d-eph makes l-meth.