(Hive Addict)
05-21-02 23:19
No 312110
(Rated as: excellent)
1) Synthetic Application of Photochemical Electron Transfer to Direct Amination of Arenes by Ammonia and Primary Amines, M. Yasuda, T. Yamashita, T. Matsumoto, K. Shima, and C. Pac, J. Org. Chem., 50, 3667-3669 (1985)
2) Direct Photoamination of Arenes with Ammonia and Primary Amines in the Presence of Electron Acceptors, M. Yasuda, T. Yamashita, K. Shima, and C. Pac, J. Org. Chem., 52, 753 (1987)
3) Mechanisms for Direct Photoamination of Arenes with Ammonia and Amines in the Presence of m-Dicyanobenzene, M. Yasuda, Y. Matsuzaki, K. Shima, and C. Pac, J. Chem. Soc. Perkin Trans. 2, 1988, 745
4) Synthesis of Isoquinoline precursors by Photoamination of Stilbenes with Bifunctional Alkylamines, M. Yasuda, J. Kubo, and K. Shima, Heterocycles, 31, 1007 (1990)
5) Photoinduced Nucleophilic Addition of Ammonia and Alkylamines to Aryl-Substituted Alkenes in the Presence of p-Dicyanobenzene, T. Yamashita, K. Shiomori, M. Yasuda, and K. Shima, Bull. Chem. Soc. Jpn., 64, 366 (1991)
6) Regiochemistry on Photoamination of Stilbene Derivatives with Ammonia via Electron Transfer, M. Yasuda, T. Isami, J. Kubo, M. Mizutani, T. Yamashita, and K. Shima, J. Org. Chem., 57, 1351 (1992)
7) Stereochemical Studies on the Amination of Arenes with Ammonia and Alkylamines via Photochemical Electron Transfer, M. Yasuda, K. Shiomori, S. Hamasuna, K. Shima, and T. Yamashita, J. Chem. Soc. Perkin Trans. 2, 1992, 305
8) Application of Photoamination to Synthesis of Benzylisoquinoline, Aporphins, and Isopavines, M. Yasuda, S. Hamasuna, K. Yamano, J. Kubo, and K. Shima, Heterocycles, 34, 965-977 (1992)
9) A Convenient Method for Synthesis of 1-Amino-2-tetralones by Photoamination of 2-Alkoxynaphthalenes with Alkylamines, T. Yamashita, K. Yamano, M. Yasuda, and K. Shima, Chem. Lett., 1993, 627-630
10) Synthesis of Phenylethylamine Moiety by Photoamination of Styrene Derivatives with Ammonia, T. Yamashita, M. Yasuda, T. Isami, S. Nakazono, K. Tanabe, and K. Shima, Tetrahedron Lett., 34, 5131-5134 (1993)
11) Photoamination of 2-Alkoxynaphthalenes with Alkylamines via Electron Transfer and Its Application to Synthesis of 1-Alkylamino-2-tetralones, T. Yamashita, K. Tanabe, K. Yamano, M. Yasuda, and K. Shima, Bull. Chem. Soc. Jpn., 67, 246-250 (1994).
12) Amination of o-Alkenylphenols with Alkylamines via Photoinduced Proton Transfer, M. Yasuda, T. Sone, K. Tanabe, and K. Shima, Chem. Lett., 1994, 453-456
13) Regiochemistry on Photoamination of Methoxy-Substituted Phenanthrene via Electron Transfer, M. Yasuda, Y. Watanabe, K. Tanabe, and K. Shima, J. Photochem. Photobiol. A: Chem., 79, 61-65 (1994)
14) Photoinduced Nucleophilic Addition of Ammonia and Alkylamines to Methoxy- Substituted Styrene Derivatives, T. Yamashita, M. Yasuda, T. Isami, K. Tanabe, and K. Shima, Tetrahedron, 50, 9275-9286 (1994)
15) Photochemical Reactions of o-Alkenylphenols and 1-Alkenyl-2-naphthol with Alkylamines: Amination via Photoinduced Proton transfer, M. Yasuda, T. Sone, K. Tanabe, and K. Shima, J. Chem. Soc. Perkin Trans. 1, 1995, 459-464.
16) New Synthetic Route to Dibenzo[a,d]cycloheptenimines through Photoamination of 5-Alkoxy- and 5-Hydroxysibenzo[a,d]cycloheptenes Follwed by Trasannular Reaction with Acetic Acid, M. Yasuda, T. Wakisaka, R. Kojima, K. Tanabe, and K. Shima, Bull. Chem. Soc. Jpn., 1995, 68, 3169-3173
17) Regioselective 1,4-Addition of Ammonia to 1-Aryl-1,3-alkadienes and 1,4-Diaryl-1,3-butadienes via Photoinduced Electron Transfer, R. Kojima, T. Yamashita, K. Tanabe, T. Shiragami, M. Yasuda, and K. Shima, J. Chem. Soc. Perkin Trans. 1, 1997, 217-222
18) Intramolecular Cyclization of 1,2-Distyrylbenzene via Cation Radical Generated by Photoinduced Photoinduced Electron Transfer, R. Kojima, T. Shiragami, K. Shima, M. Yasuda, and T. Majima, Chem. Lett., 1997, 1241-1242
19) Photoamination of Alkenylnaphthalene with Ammonia via Electron Transfer, M. Yasuda, R. Kojima, R. Ohira, T. Shiragami, and K. Shima, Bull. Chem. Soc. Jpn., 71, 1655-1660 (1998)
20) Photoamination of 1,2-Diarylcyclopropanes Using 2,2'-Dialkoxy-1,1'-binaphthalene as Redox-Photosensitizer, M. Yasuda, R. Kojima, H. Tsutsui, L. A. Watanabe, J. Hobo, T. Yamashita, T. Shiragami, K. Shima Chem. Lett., 1999, 1269-1270
Photochemical C-C Bond Formation
21) Photoreactions of 1-Cyanonaphthalene with Indene in Various Solvents, M. Yasuda, C. Pac, and H. Sakurai, Bull. Chem. Soc. Jpn., 53, 502 (1980)
22) Direct Photocyanation of Arenes with Sodium Cyanide in the Presence of Electron Acceptors, M. Yasuda, C. Pac, and H. Sakurai, J. Chem. Soc., Perkin Trans. 1, 1981, 746
23) Photo-Birch Reduction of Arenes with Sodium Borohydride in the Presence of Dicyanobenzene, M. Yasuda, C. Pac, and H. Sakurai, J. Org. Chem., 46, 788 (1981)
24) The Photoreactions of Anthracene with Some Selected Tertiary Aromatic Amines in Polar Media, M. Yasuda, C. Pac, and H. Sakurai, Bull. Chem. Soc. Jpn., 54, 2352 (1981)
25) Ru(bpy)32+-Mediated Photoreduction of Olefins with 1-Benzyl-1,4-dihydronicotinamide: A Mechanistic Probe for Electron-Transfer Reaction of NAD(P)H-Model Compounds, C. Pac, M. Ihama, M. Yasuda, Y. Miyauchi, and H. Sakurai, J. Am. Chem. Soc., 103, 6495 (1981)
26) Ru(bpy)32+-Photosensitized Reactions of 1-Benzyl-1,4-dihydronicotinamide with Ary-Substituted Enones, Derivatives of Methyl Cinnamate, and Substituted Cinnamonitriles: Electron-Transfer Mechanism and Structure-Reactivity Relationships, C. Pac, Y. Miyauchi, O. Ishitani, M. Ihama, M. Yasuda, and H. Sakurai, J. Org. Chem., 49, 26 (1984)
27) Direct Phosphonation of Naphthalene and Phenanthrene with Trialkyl Phosphites via Photochemical Electron Transfer, M. Yasuda, T. Yamashita, and K. Shima, Bull. Chem. Soc., Jpn., 63, 938 (1990)
28) A Novel Type of Cyanomethylation Reaction of Diarylethenes with Acetonitrile Photosensitized by Benzophenone in the Presence of t-Butylamine, T. Yamashita, M. Yasuda, M. Watanabe, R. Kojima, K. Tanabe, and K. Shima, J. Org. Chem., 1996, 64, 6438-6441
29) Benzophenone-Photosensitized Alkylation of Arylalkenes with Acetone, Dimethyl Sulfoxide, and their Related Compounds in the Presence of tert-Butylamine, T. Yamashita, M. Watanabe, R. Kojima, T. Shiragami, K. Shima, and M. Yasuda, J. Photochem. Photobiol. A: Chem., 118, 165-171 (1998).
30) A Novel (3+2)photocycloaddition of Electron-deficient Alkenes to Diarylvinyidenecyclopropanes: Regioselective Formation of Vinylidenecyclopentanes, K. Mizuno, H. Sugita, T. Hirai, H. Maeda, Y. Otsuji, M. Yasuda, M. Hashiguchi, and K. Shima, Tetrahedron Lett., 42, 3363-3366 (2001)
Studies on Reactive Species
31) Solvent Effects on Fluorescence Quenching and Photoreactions of Naphthalene-Olefin and Furan Systems. Qualitative Consideration on Electronic Structures and Reactivities of Nonemissive Exciplexes, C. Pac, M. Yasuda, K. Shima, and H. Sakurai, Bull. Chem. Soc, Jpn., 55, 1605 (1982)
32) Salt-Induced Photoamination of Arenes by Aliphatic Amines via Arene/p-Dicyanobenzene Exciplexes. A Mechanism for Salt Effects on Charge Separation of Exciplexes, M. Yasuda, Y. Matsuzaki, T. Yamashita, and K. Shima, Chem. Lett., 1989, 551
33) Salt-Induced Photoamination of Arenes by Aliphatic Amines via Arene/p-Dicyanobenzene Exciplexes. A Mechanism for Salt Effects on Charge Separation of Exciplexes, M. Yasuda, Y. Matsuzaki, T. Yamashita, and K. Shima, Chem. Lett., 1989, 551
34) エキシプレックスを経由するフェナントレン
35) Unusual Effects of Acetate Ion on Photosensitized Oxygenation of Naphthalene Derivatives via Electron Transfer, T. Yamashita, T. Tsurusako, M. Yasuda, and K. Shima, Chem. Lett., 1991, 1487
36) Electron-Trsansfer Photosensitized Oxygenation of Stilbene and Naphthalene Derivatives in the Presence of Acetate Ion. Controlling the Reaction of the Cation Radicals by Weak-Nucleophilic Salts, T. Yamashita, T. Tsurusako, N. Nakamura, M. Yasuda, and K. Shima, Bull, Chem. Soc. Jpn., 66, 857-862 (1993)
37) Fluorescence Study on Polar Intramolecular Exciplexes of 9-(Phenanthroxy)alkyl p-Cyanobenzoates, M. Yasuda, G. Kuwamura, and K. Shima, J. Photochem. Photobiol. A: Chem., 86, 127-131 (1995).
38) Solvent Parameter Based on the Exciplex Emission of (2-Naphthoxy)polyalkyl p-Cyanobenzoates, M. Yasuda, Y. Kawahito, K. Sasano, Y. Andou, T. Shiragami, and K. Shima, Photochem. Photobiol.. A: Chem., 121, 149-155 (1999).
Photochemistry of Strained Molecules
39) Photosensitized Ring-Cleavage Reactions of 2,2-Diaryloxetanes by Aromatic Nitriles, K. Nakabayashi, J. Kojima, K. Tanabe, M. Yasuda, and K. Shima, Bull. Chem. Soc. Jpn., 62, 96 (1989).
40) Photochemical Ring-Cleavage Reactions of 2,2-Diaryloxetanes in the Presence of Electron Donor, K. Nakabayashi, S. Fujimura, M. Yasuda, and K. Shima, Bull. Chem. Soc. Jpn., 62, 2733 (1989)
41) Ring-Splitting Reaction of 2,2-Diarylthietane by Electron-Transfer Photosensitization of 9,10-Dicyanoanthracene, K. Shima, A. Sazaki, K. Nakabayashi, and M. Yasuda, Bull. Chem. Soc. Jpn., 65, 1472-1474 (1992)
42) Efficient Cross-Photocycloadditions of Vinylcoumarins to Olefins, M. Yasuda, T. Kishi, C. Goto, H. Satoda, K. Nakabayashi, T. Minami, and K. Shima, Tetrahedron Lett., 33, 6465-6468 (1992)
43) Cycloreversion of Aryl-Substituted Cyclobutene by Direct Photolysis and Pulse Radiolysis, K. Nakabayashi, Y. Tahara, M. Yasuda, K. Shima, and S. Takamuku, Bull. Chem. Soc. Jpn., 66, 698-702 (1993).
44) Mechanistic Studies for Cross-Photocycloadditions of 3-Vinylcoumarin Derivativres to Electron-Rich Olefins, M. Yasuda, T. Kishi, C. Goto, H. Satoda, and K. Shima, J. Photochem. Photobiol. A: Chem., 76, 61-67 (1993)
45) Cycloreversion of 1-(1-Naphtyl)-5-phenylbicyclo[3.2.0]hept
Other Synthetic Studies than Photochemical Reaction
46) Reductant-induced Homolysis of the Thallium-Carbon Bond: Novel Oxygenation of Alkylthallium (III) Compounds with Ascorbic Acid, H. Kurosawa and M. Yasuda, J. Chem. Soc. Chem. Comm., 1978, 716
47) Homolysis of the Tl-C Bond in Hydrodethallation of Alkylthallium (III) Compounds with N-Benzyl-1,4-dihydronicotinamide, H. Kurosawa, H. Okada, and M. Yasuda, Tetrahedron Lett., 21. 959 (1980)
48) Acid-Catalysed Rearangements of [4.3.2]- and [3.3.3]Propellanes Tricyclo[4.3.2.01,5]- undecanes, and Tricyclo[6.3.0.01,5]undecanes, K. Kakiuchi, M. Ue, I. Wakaki, Y. Tobe, Y. Odaira, M. Yasuda, and K. Shima, J. Org. Chem., 51, 281 (1986)
49) Solvolytic Rearrangement of 5,6-Polymethylenebicyclo[4.2.0]octan-2-o
50) Novel Rearrangement of 5,6-Disubstituted Bicyclo[4.2.0]octan-2-ones with AlCl3. Application to Total Synthesis of (±)-5-Oxosilphiperfol-6-ene and (±)-Silphiperfol-6-ene, K. Kakiuchi, M. Ue, H. Tsukahara, T. Shimizu, T. Miyao, Y. Tobe, Y. Odaira, M. Yasuda, and K. Shima, J. Am. Chem. Soc., 111, 3707 (1989).
Reactivity-Structure Relationships
51) Molecular Structures of Diarylcyclobutanes Associated with Reactivities in Ring-CleavageReactions: Implications of Conformationally Controlled Through-Bond Coupling, K. Shima, J. Kimura, K. Yoshida, M. Yasuda, K.Imada, and C. Pac, Bull. Chem. Soc. Jpn., 62, 1934 (1989).
52) Thermal Ring-Splitting Reactions of Diarylcyclobutanes: Significance of Steric Effects on Orbital Interactions in Transition States and Biradical Intermediates, M. Yasuda, K. Yoshida, K. Shima, C. Pac, and S. Yanagida, Bull. Chem. Soc. Jpn., 62, 1943 (1989)
53) Cycloreversion of 1,4-Diphenylbicyclo[3.2.0]hept-2-ene under Triplet Sensitization. An Adiabatic Process on the Triplet Surface, K. Nakabayashi, W. Fukumoto, M. Yasuda, K. Shima, and S. Takamuku, Chem. Lett., 1992, 803-806
54) Photochemical Reactions of 1,4-Dicyanonaphthalene with Allylic Silanes: Control of Reaction Modes by Use of Solvent and Additive Effects, K. Mizuno, K. Terasaka, T. Nishiyama, M. Yasuda, K. Shima, T. Tamai, and Y. Otsuji, Tetrahedron, 48, 9673-9686 (1992)
55) Dehydroamination Reactions of 9-Amino-9,10-dihydrophenanthrene and Related Compounds by Thermolysis, M. Yasuda, T. Harada, Y. Ansho, and K. Shima, Bull. Chem. Soc. Jpn., 66, 1451-1455 (1993)
56) Highly Twisted tert-Butoxycarbonyl in Hexa-tert-Butyl Benzenehexacarboxylate. The Structural Origin of Steric Hindrance-Induced Dual Fluorescence, M. Yasuda, G. Kuwamura, T. Nakazono, K. Shima, Y. Inoue, N. Yamasaki, and A. Tai, Bull. Chem. Soc. Jpn., 67, 505-510 (1994).
57) A Carbon-Centered Radical as a Reaction Species in the DNA Strand-Breakage by D-Glucosamine, T. Yamaguchi, N. Kashige, S. Matsumoto, K. Satoh, M. Yasuda, and K. Watanabe, Biol.Pham. Bull., 1998, 21, 205-209.
58) Copper Biosorption by Chemically Treated Micrococcus luteus Cells, A. Nakajima, M. Yasuda, H. Yokoyama, H. Ohya-Nishiguchi, and H. Kamada, World J. Microbiology Biotechnology, 17, 343-347 (2001)
Flavin Photochemistry
59) Remarkable Effect of Surfactant on Flavin Photochemistry. Monomerization of Thymine Cyclobutane Dimers Photosensitized by Flavins in the Presence of SDS in Aqueous Solution, M. Yasuda, T. Nakazono, T. Hamasaki, Y. Nishinaka, N. Nakamura, C. Pac, and K. Shima, Chem. Lett., 1995, 563-564.
60) Photochemistry of Flavins in Micelles: Specific Effects of Anionic Surfactants on the Monomerization of Thymine Cyclobutane Dimers Photosensitized by Tetra-O-acylriboflavins, M. Yasuda, Y. Nishinaka, T. Nakazono, T. Hamasaki, N. Nakamura, T. Shiragami, C. Pac, and K. Shima, Photochem. Photobiol.., 1998, 67, 192- 97.
Photochemistry of High Valent Metalloporphyrin Complexes
61) Fluorescence Responces on Ion Recognition with 2-(4-Dialkylaminophenyl)ethoxyantimony(V
62) Synthesisi and Fluorescence Study of (2-Naphthoxy)polyoxalkoxyantimony(V) Tetraphenylporphyrin Complex, Y. Andou, T. Shiragami, K. Shima, and M. Yasuda, J. Photochem. Photobiol. A: Chem. In press
63) Effects of Axial Ligands on Reduction Potentials, Proton Dissociation, and Fluorescence Quantum Yield of Hydrooxoporphyrinatoantimony(V) Complexes, T. Shiraga,i, Y. Andou, Y. Hamasuna, F. Yamaguchi, K. Shima, and M. Yasuda, Bull. Chem. Soc. Jpn., in press.
Review
1) 光電子移動反応による活性化ー芳香核と求核
2) Amination of Electron-Rich Substrates via Photoinduced Electron Transfer: Mechanism and Synthetic Application, M. Yasuda and K. Shima, Reviews on Heteroatom Chemistry, 4, 27 (1991)
3) Application of Photoinduced Nucleophilic Addition Reaction to Organic Synthesis, M. Yasuda and K. Shima,Trends in Organic Chemistry, 4, 291-302 (1993)
4) Photoamination Directed toward the Synthesis of Heterocyclic Compounds, M. Yasuda, T. Yamashita, R. Kojima, and K. Shima, Heterocycles, 43, 2513-2522 (1996)
5) Photoamination via Electron Transfer, M. Yasuda, T. Yamashita, T. Shiragami, and K. Shima, Recent Reasearch Deveolpment in Photochemistry & Photobiology, 3 65-76 (1999)
6) 汎用性の る光化学反応をめざして：光アミノ化反応, 保田昌秀，志摩健介、光化学，30, No. 3, 215-222 (1999).
7) Photochemical Polar Addition, Handbook of Photochemistry and photobiology, American Scientifin Publishers, in press
特許
1) アンチモンポルフィリン光触媒、保田昌秀、
2) 光触媒装置、保田昌秀、白上 努、信原一敬
05-22-02 00:48
(Rated as: insignificant)