Jubrail
(Hive Addict)
07-13-03 22:09 No 446880 |
|
Bookmark | ||||||
Just one of many chem questions that plague me due to my unfortunate ignorance and predisposition for the humanities and not the natural sciences. OK, SO2: S has 6 valence e- and same with O. So wouldn't it make sense for S to form a double bond with EACH O atom? (As in O=S=O) Yet we know that SO2 is O=S-O [leaving the S with 3 unpaired valence shell electrons?]; well, acutally it looks a bit different because of delocalization. So, obviously I have a poor grasp of this very simple octet rule. If one of my fellow bees, so wise in the ways of chemistry could help this little dolt, it woiuld be appreciated. Rainbows & Butterflies Forever :) |
||||||||
acid_egg (Hive Addict) 07-14-03 02:03 No 446924 |
SO2 | Bookmark | ||||||
OK, SO2: S has 6 valence e- and same with O. So wouldn't it make sense for S to form a double bond with EACH O atom? (As in O=S=O) Sulphur can have -2,0,+2,+4 and +6 oxidation states and in the case of SO2 it's +4 ie it shares four unpaired electrons and therefore is O=S=O Find out about s,p,d orbitals etc. |
||||||||
Jubrail (Hive Addict) 07-14-03 16:31 No 447076 |
I did | Bookmark | ||||||
Just learn about the s,p,d orbitals. OK, in SO2, then, there are 6 shared electrons, as there are 3 non-H atoms and 18 available valence electrons. Next question, though: In diagramming electron geometric configurations according to molecular orbital theory, how do I know when to use a pi bond or a pi* bond? Ditto for sigma, of course. I appreciate the help. Thanks a lot for the help acid_egg Rainbows & Butterflies Forever :) |
||||||||
java (Hive Bee) 07-14-03 17:37 No 447101 |
Re; Basic chem help | Bookmark | ||||||
Try going here and check out orbitals, http://www.colby.edu/chemistry/OChem/dem We're all in this world together, http://www.chiapaslink.ukgateway.net/ |
||||||||
Jubrail (Hive Addict) 07-14-03 21:00 No 447162 |
thanks | Bookmark | ||||||
for all your help Rainbows & Butterflies Forever :) |
||||||||
torture (Stranger) 07-17-03 18:41 No 448060 |
Re: OK, SO2: S has 6 valence e- and same with... | Bookmark | ||||||
|
||||||||
acid_egg (Hive Addict) 07-17-03 19:59 No 448069 |
what?? | Bookmark | ||||||
This question didn't really make sense from the start and the thread is becoming increasingly non-sensical. This is the electronic configuration of sulphur in the ground state http://www.webelements.com/webelements/e Sulphur however has easily accessable 3d orbitals which means it's 3s and 3p electrons can move to the 3d orbitals giving a greater number of unpaired electrons. So in the case of SO2 picture one of the 3px electrons having moved to the 3dx orbital. Thus there are now four unpaired electrons, 2 for each oxygen in the case of SO2. In SF6 the sulphur nucleus actually has a compliment of 12 valence electrons. |
||||||||