(Hive Bee)
01-21-03 16:19
No 400186
(Rated as: excellent)
Here's a few interesting starting points for alternative reaction methods. Some may have been posted before. If you have the time, check them out. (I don't have the spare time right now)
Cleavage of Ketoximes to Ketones Using Wet Silica/ Sodium Periodate: Tetrahedron Lett., 38, 8819 (1997)
Oxidation of Benzoins to Benzils–Oxone/Wet Alumina: Molecules Online, 2, 82 (1998)
General Oxidation Reaction-Claycop [Copper(II) nitrate/Clay]/H2O2: Tetrahedron Lett.,39, 1307 (1998)
Reduction of Nitrocompounds to Amines on Alumina-supported Hydrazine: Tetrahedron Lett. 42, 5347 (2001)
Sec- & Tert-Amines via Reductive Amination of Carbonyls-NaBH4/Wet Clay: Tetrahedron,54, 6293 (1998)
Selective Oxidation of Styrene to Acetophenone - Ionic Liquids/CO2/H2O2, Green Chem., 4, 170 (2002)
Solvent-free Preparation of Ionic Liquids Using a Household MW Oven, Pure & Applied Chem., 73, 1309 (2001)
MW-expedited Epoxidation of Olefins over Hydrotalcites Using H2O2, Tetrahedron Lett,43, 2909 (2002)
Urea-Hydrogen Peroxide Complex: Solid State Oxidative Protocols for Hydroxylated ALdehydes and Ketones (Dakin Reaction), Nitriles, Sulfides and Nitrogen Heterocycles. Organic Letters, 189 (1999)
b-Nitrostyrenes-Side Chain Nitration of Styrenes with Clayfen/Clayan: Tetrahedron Lett., 39, 3977 (1998)
Solvent-free Syntheses on Mineral Supports Using MW Irradiation: Clean Products & Processes,1,132 (1999)
