| |
|
LeberBioMed
03-23-04 21:44
|
|
|
|
<a href="https://www.the-hive.ws/forum/showflat.pl?Number=496882&page=21&view=&sb=&Search=&vc=&new=&start=0&xrated=y&&URLForums=" title="Click here to show this downrated post">Good way to make Thionyl chloride</a>
<br>
<i title="This post has been downrated by the moderators">(Rated as: misinforming)</i>
</td>
<td class="text_bg" align="right" valign="top">
</td>
<td> </td>
</tr>
<tr class="text_bg">
<td align="left" valign="bottom"><img src="../forum/images/left_bottom.gif" border="0" height="12" width="9"></td>
<td valign="middle" align="center" colspan="7"> </td>
<td align="right" valign="bottom"><img src="../forum/images/right_bottom.gif" border="0" height="12" width="9"></td>
</tr>
<tr class="page_bg">
<td colspan="9"> </td>
</tr>
<td align="left" valign="top" class="text_bg">
<img src="../forum/images/left_top.gif" border="0" height="12" width="9"></td>
<td colspan="7"><a name="Post496900"></a></a> </td>
<td align="right" valign="top"><img src="../forum/images/right_top.gif" border="0" height="12" width="9"></td>
</tr>
<tr class="text_bg">
<td rowspan="2"> </td>
<td rowspan="2"> </td>
<td valign="top" align="center" rowspan="2">
Megatherium<br>
<i>(<span title="The user's title at the time of posting">Hive Bee</span>)</i><br>
<span title="Posting date">03-23-04 23:46</span><br>
<span title="Link to this post by using the markup [496900]">No 496900</span><br>
</td>
<td rowspan="2"> </td>
<td rowspan="2" width="1" class="vert_ruler">
<img src="../forum/images/hr.gif" border="0" width="1" height="1">
</td>
<td rowspan="2"> </td>
<td class="text_bg" align="left" valign="top">
<b title="The subject of this post">This violates the rules ...</b>
</td>
<td class="text_bg" align="right" valign="top">
</td>
<td> </td>
</tr>
<tr class="text_bg">
<td colspan="2" valign="top" align="left">
<br>
... because what you post is absolute nonsense.<br><br>Thionyl chloride is prepared by the following reaction:<br>SO<sub>2</sub> + PCl<sub>5</sub> --> SOCl<sub>2</sub> + POCl<sub>3</sub><br><br>Someone who knows a thing or two about chemistry will appreciate that this is no kitchen procedure <img src="../forum/images/icons_lightgrey/tongue.gif" alt="tongue" title="Tongue" heigth="15" width="15">.
</td>
<td> </td>
</tr>
<tr class="text_bg">
<td align="left" valign="bottom"><img src="../forum/images/left_bottom.gif" border="0" height="12" width="9"></td>
<td valign="middle" align="center" colspan="7"> </td>
<td align="right" valign="bottom"><img src="../forum/images/right_bottom.gif" border="0" height="12" width="9"></td>
</tr>
<tr class="page_bg">
<td colspan="9"> </td>
</tr>
<td align="left" valign="top" class="text_bg">
<img src="../forum/images/left_top.gif" border="0" height="12" width="9"></td>
<td colspan="7"><a name="Post497006"></a></a> </td>
<td align="right" valign="top"><img src="../forum/images/right_top.gif" border="0" height="12" width="9"></td>
</tr>
<tr class="text_bg">
<td rowspan="1"> </td>
<td rowspan="1"> </td>
<td valign="top" align="center" rowspan="1">
LeberBioMed<br>
<span title="Posting date">03-24-04 09:12</span><br>
</td>
<td rowspan="1"> </td>
<td rowspan="1" width="1" class="vert_ruler">
<img src="../forum/images/hr.gif" border="0" width="1" height="1">
</td>
<td rowspan="1"> </td>
<td class="text_bg" align="left" valign="top">
<b title="The subject of this post">
<a href="https://www.the-hive.ws/forum/showflat.pl?Number=497006&page=21&view=&sb=&Search=&vc=&new=&start=0&xrated=y&&URLForums=" title="Click here to show this downrated post">Oh ya</a>
</b><br>
<i title="This post has been downrated by the moderators">(Rated as: misinforming)</i>
</td>
<td class="text_bg" align="right" valign="top">
</td>
<td> </td>
</tr>
<tr class="text_bg">
<td align="left" valign="bottom"><img src="../forum/images/left_bottom.gif" border="0" height="12" width="9"></td>
<td valign="middle" align="center" colspan="7"> </td>
<td align="right" valign="bottom"><img src="../forum/images/right_bottom.gif" border="0" height="12" width="9"></td>
</tr>
<tr class="page_bg">
<td colspan="9"> </td>
</tr>
<td align="left" valign="top" class="text_bg">
<img src="../forum/images/left_top.gif" border="0" height="12" width="9"></td>
<td colspan="7"><a name="Post497022"></a></a> </td>
<td align="right" valign="top"><img src="../forum/images/right_top.gif" border="0" height="12" width="9"></td>
</tr>
<tr class="text_bg">
<td rowspan="2"> </td>
<td rowspan="2"> </td>
<td valign="top" align="center" rowspan="2">
ApprenticeCook<br>
<i>(<span title="The user's title at the time of posting">Hive Bee</span>)</i><br>
<span title="Posting date">03-24-04 13:27</span><br>
<span title="Link to this post by using the markup [497022]">No 497022</span><br>
</td>
<td rowspan="2"> </td>
<td rowspan="2" width="1" class="vert_ruler">
<img src="../forum/images/hr.gif" border="0" width="1" height="1">
</td>
<td rowspan="2"> </td>
<td class="text_bg" align="left" valign="top">
<b title="The subject of this post">huh?</b>
</td>
<td class="text_bg" align="right" valign="top">
</td>
<td> </td>
</tr>
<tr class="text_bg">
<td colspan="2" valign="top" align="left">
<br>
.... so what are you going to do? have a SO<sub>2</sub> generator bubble through HCl??? SO<sub>2</sub> is nasty shit, swim had his lab full of it a few months back, nasty acid spill... via stupidity...<br><br>So if that reaction worked it would be possible but shit it would be a danger filled one if not done correctly...
</td>
<td> </td>
</tr>
<tr class="text_bg">
<td align="left" valign="bottom"><img src="../forum/images/left_bottom.gif" border="0" height="12" width="9"></td>
<td valign="middle" align="center" colspan="7"> </td>
<td align="right" valign="bottom"><img src="../forum/images/right_bottom.gif" border="0" height="12" width="9"></td>
</tr>
<tr class="page_bg">
<td colspan="9"> </td>
</tr>
<td align="left" valign="top" class="text_bg">
<img src="../forum/images/left_top.gif" border="0" height="12" width="9"></td>
<td colspan="7"><a name="Post497037"></a><a name="last"></a></a> </td>
<td align="right" valign="top"><img src="../forum/images/right_top.gif" border="0" height="12" width="9"></td>
</tr>
<tr class="text_bg">
<td rowspan="2"> </td>
<td rowspan="2"> </td>
<td valign="top" align="center" rowspan="2">
Organikum<br>
<i>(<span title="The user's title at the time of posting">Wonderful Personality</span>)</i><br>
<span title="Posting date">03-24-04 15:16</span><br>
<span title="Link to this post by using the markup [497037]">No 497037</span><br>
</td>
<td rowspan="2"> </td>
<td rowspan="2" width="1" class="vert_ruler">
<img src="../forum/images/hr.gif" border="0" width="1" height="1">
</td>
<td rowspan="2"> </td>
<td class="text_bg" align="left" valign="top">
<b title="The subject of this post">The common industrial method for producing...</b>
</td>
<td class="text_bg" align="right" valign="top">
</td>
<td> </td>
</tr>
<tr class="text_bg">
<td colspan="2" valign="top" align="left">
<br>
The common industrial method for producing thionylchloride is to treat SO2 or SO3 with SCl2 at 150°C to 250°C in the presence of activated carbon.<br>SO3 + SCl2 = SOCl2 + SO2<br>SO2 + SCl2 + Cl2 = 2SOCl2 (the chlorine comes from the SCl2 which is unstable and dissociates into S2Cl2 and Cl2)<br><br>S2Cl2 is formed by the direct combination of the elements.<br>SCl2 is formed by passing the correct amount of Cl2 into S2Cl2.<br><br>Ref: Ullmanns 2002.
<br>
<span title="The signature"><hr><center><b><font color="blue">Shareholder of Paranoid Fucks inc. </center></b></font color="blue"></span>
</td>
<td> </td>
</tr>
<tr class="text_bg">
<td align="left" valign="bottom"><img src="../forum/images/left_bottom.gif" border="0" height="12" width="9"></td>
<td valign="middle" align="center" colspan="7"> </td>
<td align="right" valign="bottom"><img src="../forum/images/right_bottom.gif" border="0" height="12" width="9"></td>
</tr>
<tr class="page_bg">
<td colspan="9"> </td>
</tr>
</body>
</html>
|
