skanic
(Newbee) 07-15-04 13:14 No 519549 |
ester synthesis | |||||||
will i have a triglyceride if i mix 3 parts oil (or butter) in 1 part of glycerol ? |
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skanic (Newbee) 07-15-04 14:15 No 519553 |
and if i had a little h2so4 ? | |||||||
and if i had a little h2so4 ? |
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Rhodium (Chief Bee) 07-15-04 14:20 No 519556 |
Fischer esterification | |||||||
Heating aliphatic carboxylic acids with glycerol (and optionally a catalytic amount of a strong mineral acid) will esterify the components to form various triglyceride esters. The procedure is called Fischer esterification. It will not happen at room temperature (>100°C is suitable) or in aqueous solution. Neither "oil" or "butter" could be classified as "aliphatic carboxylic acids" though. Stearic acid could, however, and is the main constituent of top-grade old-style candles. Here is a PPT presentation dealing with the esterification of Glycerol with Stearic Acid, forming Tristearin (a triglyceride ester): http://www.chem.uic.edu/wardrop/teaching The Hive - Clandestine Chemists Without Borders |
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skanic (Newbee) 07-15-04 14:36 No 519565 |
an other question | |||||||
thank you. You will take me for a fool but i don't understand something, Do fatty acids that are in oil (corn oil for example) are separated(one by one) OR are they assembled together in complexes (triglycerides) ? please repond |
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Rhodium (Chief Bee) 07-15-04 15:16 No 519575 |
Free fatty acids are relatively uncommon | |||||||
Both vegetabilic oils and animal fats come as triglyceride molecules: http://users.rcn.com/jkimball.ma.ultrane Free fatty acids are relatively uncommon to find in large amounts in nature: http://en.wikipedia.org/wiki/Fat The Hive - Clandestine Chemists Without Borders |
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