3base (Hive Bee) 06-09-02 15:29 No 319108 |
alkyl halides from aq.HBr/HI & alcohols (Rated as: excellent) |
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several alkyl halides were prepared directly from the alcohols and hydrobromic/hydroiodic acid. a general recipe is given and the particular peculiarities of each alkyl halide were regarded. methanol + aq.HBr --> methyl bromide methanol + aq.HI --> methyl iodide ethanol + aq.HBr --> ethyl bromide ethanol + aq.HI --> ethyl iodide isopropanol + aq.HBr --> isopropyl bromide isopropanol + aq.HI --> isopropyl iodide ... american chemical journal, 1907 38: 627-642 "on the base-forming property of carbon" james f norris |
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