02-09-03 00:58
No 405744
Does anyone have the time to ponder whether something useful could be done with 1-phenyl-2-thiourea?
I had in mind this unwatched compound being reacted in such a way that the yield would be bromobenzene + by products.
In a similar fashion, I wonder whether 1-allylthiourea could yield somehow allylbromide/allylchloride/allyliodide?
See what I'm getting at here?
followed by grignard reagent
(Hive Bee)
02-09-03 02:17
No 405757
Poison..............
Safety data for 1-phenyl-2-thiourea
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General
Synonyms: phenylthiocarbamide, phenylthiourea, alpha-phenylthiourea, N-phenylthiourea, 1-phenylthiourea, PTC, PTU, U 6324, USAF EK-1569
Use: rodenticide
Molecular formula: C7H5NHCSNH2
CAS No: 103-85-5
EINECS No:
Physical data
Appearance: white crystalline powder
Melting point: 154 C
Boiling point:
Vapour density:
Vapour pressure:
Density (g cm-3): 1.3
Flash point:
Explosion limits:
Autoignition temperature:
Water solubility: negligible
Stability
Stable. Incompatible with strong acids, strong oxidizing agents, strong bases.
Toxicology
Poison. Highly toxic - may be fatal if swallowed or inhaled. Note low LD50s below. Experimental teratogen. Irritant.
Toxicity data
(The meaning of any abbreviations which appear in this section is given here.)
ORL-RAT LD50 3 mg kg-1
IPR-RAT LD50 5 mg kg-1
ORL-MUS LD50 10 mg kg-1
IPR-MUS LD50 25 mg kg-1
ORL-RBT LD50 40 mg kg-1
Risk phrases
(The meaning of any risk phrases which appear in this section is given here.)
R23 R24 R25.
Transport information
(The meaning of any UN hazard codes which appear in this section is given here.)
UN No 2767. Packing group I. Hazard class 6.1.
Personal protection
Safety glasses, gloves, good ventilation, dust mask if powdered product may get into the atmosphere.
Judging by the data you should find something else to cook with so you may cook tomorrow...........java