Rhodium
(Chief Bee) 08-28-01 08:18 No 208019 |
p-benzoquinone addition mechanism? | Bookmark | ||||||
p-Benzoquinone reacts with trialkylboranes to give 2,5-dihydroxyalkylbenzenes, with sodium thiosulfate to give 2,5-dihydroxyphenylthiosulfate etc. What is the mechanism behind this? What other stuff can generally be added to p-benzoquinone? I would very much like to have some kind of review article on addition to benzoquinone, besides the obvious diels-alder pericyclic addition. Anyone here who could help me with a reference of some sort? |
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Natrix (Stranger) 09-11-01 01:58 No 212019 |
Re: p-benzoquinone addition mechanism? | Bookmark | ||||||
I'm not sure if this: http://www.geocities.com/i998877/ is what you are looking for. I hope you can read it. |
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Rhodium (Chief Bee) 09-11-01 06:13 No 212047 |
Re: p-benzoquinone addition mechanism? | Bookmark | ||||||
Thank you, exactly what I'm looking for. What reference is it taken from, Chemishe Berichte? I don't want to be picky when I got all this from you, but the pages 608, 616 and 620 is missing, and there are doublets of 622, 623 and 625 in their places... |
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Natrix (Stranger) 09-12-01 05:16 No 212523 |
Re: p-benzoquinone addition mechanism? | Bookmark | ||||||
The documents are from Houben-Weyl: Methoden der organischen Chemie ( http://www.indiana.edu/~cheminfo/h-wguid |
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Natrix (Stranger) 09-14-01 03:51 No 213462 |
Re: p-benzoquinone addition mechanism? | Bookmark | ||||||
should be o.k. now: http://www.geocities.com/hon5rrnfd/ and there is other stuff at: http://www.geocities.com/x6534fzz/ |
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