[vanillin.eugenol.demethylation.methylation]  [2-heac.nitroaldol.condensation]  [nabh4.copper.reduction]  [zn.hcl.reduction]  [back]

 A new ionic liquid- 2-hydroxy ethylammonium formate, N. Bicak, Istanbul Technical University, Turkey, 04.08.2003. [pdf]
 2-Hydroxyethyl-ammonium carboxylates - highly biodegradable and slightly toxic ionic liquids, A. Zicmanis et al., University of Latvia, Riga, 05.08.2010. [pdf]
 2-Hydroxyethylammonium Formate as a Recyclable Promoter and Medium for the Green Synthesis of b-Nitrostyrenes, A. Alizadeh et al., Razi University, Iran, 28.08.2010. [pdf]
 Synthesis of bm-nitrostyrene in highly hydrophilic Ionic Liquid media, S. Pavlovica et. al, University of Latvia, Riga, 20.11.2012. [pdf]
 P2NP-derivation to the alternative approach!, Oerlikon, The Vespiary - Drug Synthesis & Extraction, 01.12.2017.  [wathever9999]  [pdf]
 MDP2NP - 2-HEAA catalysed Henry condensation, xdragon, The Vespiary - Drug Synthesis & Extraction, 26.07.2020.  [pdf]

substrat mw g product mw cas mp
2,5-Dimethoxybenzaldehyde 166.17 1.66 1-(2,5-Dimethoxyphenyl)-2-Nitroethene 209.20
2,5-dimethoxy-4-(ethylthio)benzaldehyde 226.29 2.26 2-[2,5-Dimethoxy-4-(ethylthio)phenyl]-2-Nitroethene 269.92
2,5-dimethoxy-4-(propylthio)benzaldehyde 240.32 2.40 2-[2,5-Dimethoxy-4-(propylthio)phenyl]-2-Nitroethene 283.34
4-Fluorobenzaldehyde 124.11    1.24    1-(4-Fluorophenyl)-2-Nitropropene 181.16    775-31-5
3,4,5-Trimethoxybenzaldehyde   196.20 1.96 1-(3,4,5-Trimethoxyphenyl)-2-Nitroethene 239.22
2,4,5-Trimethoxybenzaldehyde 196.20 1.96 1-(2,4,5-Trimethoxyphenyl)-2-Nitropropene 253.25 17231-84-4    98-99
3.4-Methylenedioxybenzaldehyde    150.14    1.50    1-(3,4-Methylenedioxyphenyl)-2-Nitropropene    207.18   
 
2-Aminoethanole 61.08 3.05
Glacial Acetic Acid 60.05 3.30
Formic Acid 46.03 2.30
Nitroethane 75.07 0.83
Nitromethane 61.04 0.67