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Rhodium (Chief Bee) 03-13-04 07:14 No 494847 |
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Peroxydisulfate Isosafrole Oxidation (Rated as: excellent) |
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This is a procedure which turns isosafrole to the diacetoxyglycol in 71% yield, and this can then of course easily be rearranged to MDP2P, maybe with Chromics novel high-yielding hydrochloric acid method, adapted to the preparation of MDP2P in Post 476334 (Chromic: "HCl is so good it's GOLDEN!", Chemistry Discourse) after a procedure published in the following article: Post 476342 (Rhodium: "Effect of various acids on pinacol rearrangement", Chemistry Discourse) Electron-transfer Processes: Oxidation of ![]() ![]() Attilio Citterio, Claudio Arnoldi, Claudio Giordano, Graziano Castaldi J. Chem. Soc. Perkin Trans. 1. 891-896 (1983) (../rhodium/pdf /diacetoxylat Abstract Oxidation of ![]() ![]() Another reference related to this article has been posted in Post 487882 (Rhodium: "Oxidation of styrenes by peroxydisulfate-Cu(II)", Stimulants) The Hive - Clandestine Chemists Without Borders |
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