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Methyl mans Benzoquinone Wacker
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pekebaz3

Joined: 10 Jun 2005
Posts: 21
805.86 Points

Sat Jul 09, 2005 10:49 am
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Can methyl mans Benzoquinone Wacker Oxidation of Safrole in Methanol be sized up?
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alkadelic

Joined: 14 Jun 2005
Posts: 7
224.90 Points

Tue Aug 09, 2005 6:24 am
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im sure it can.. what i want to know is, whats the most it could be sized up in a two liter flask. im going to try and double it. ill post results later, but if someone has sized up to 3 times in two liter, please post!! its certainly not in the rhodium archives.
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ApprenticeCook
DILLIGAF
Joined: 12 Feb 2005
Posts: 162
Location: Australia
8486.38 Points

Tue Aug 09, 2005 10:11 am
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you can size up MOST reactions, however limits do apply, the reactivity of some processes will overpower the vessel if made to large (resulting in shards of glass and many many tears). So yes you can, just dont go making it 500x bigger, 2x or 3x is ok.
However remember to maintain your ratios.

-AC
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KrZ

Joined: 18 Jul 2005
Posts: 11
Location: Pyongyang, DPRK
348.04 Points

Tue Aug 09, 2005 7:21 pm
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It's not particularly exothermic or anything. Actually it's a very sexy little reaction, SWIM performed it at very large scale back in the beginning, 12L carboy with about 6L of reactants. Hard on the wallet though considering the amount of PdCl2 one needs for good results.
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